6-Benzylaminopurine CAS:1214-39-7

  • Product Name:6-Benzylaminopurine
  • CAS:1214-39-7
  • Molecular formula:C12H11N5
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6-Benzylaminopurine CAS:1214-39-7

6-Benzylaminopurine CAS:1214-39-7 Basic information

Product Name: 6-Benzylaminopurine
Synonyms: 6-Benzylaminopurine, for plant cell culture,≥99.0%;6-(Benzylamino)-1H-purine;6-Benzylamino-1H-purine;6–BENZYLADENINE (BA);6-Benzylaminopurine,99%;6-BENZYLAMINOPURINERESEARCH GRADE;6-Benzylaminopurine,BA, N6-Benzyladenine;6-BenzylaMinopurine, 99% 5GR
CAS: 1214-39-7
MF: C12H11N5
MW: 225.25
EINECS: 214-927-5
Product Categories: plantgrowth;Pharmaceutical Raw Materials;Miscellaneous;Purine;Amines;PLANT GROWTH REGULATOR;Biochemistry;Cytokinins;Nucleobases and their analogs;Nucleosides, Nucleotides & Related Reagents;Plant Growth Regulators;Plant Hormones
Mol File: 1214-39-7.mol

6-Benzylaminopurine CAS:1214-39-7 Chemical Properties

density: 0.899 g/mL at 20 °C
Melting point: 230-233 °C
Boiling point: 145 °C(lit.)
form: Liquid
storage temp.: 2-8°C
Water Solubility: Soluble in water, methanol and acetone. Slightly soluble in ethyl acetate and dichloromethane and toluene. Insoluble in n-hexane.
refractive index: n20/D 1.418(lit.)
pka: 9.36±0.20(Predicted)
BRN: 19406
InChIKey: NWBJYWHLCVSVIJ-UHFFFAOYSA-N
Fp: 103 °F
solubility: H2O: soluble
NIST Chemistry Reference: 1H-purin-6-amine, n-(phenylmethyl)-(1214-39-7)
Stability: Stable. Incompatible with strong oxidizing agents.
vapor pressure: 3.3 mm Hg ( 20 °C)
vapor density: >1 (vs air)
Odor: Characteristic acrylic.
CAS DataBase Reference: 1214-39-7(CAS DataBase Reference)
EPA Substance Registry System: N-Benzyladenine (1214-39-7)

The Usage and Dosage of 6-BA Used on Different Crops

Crops

Dosage

(mg/L)

Method of use

Effects

Rice

10

Foliage spray rice seedlings

Increase survival rate

Watermelon, muskmelon, pumpkin etc

100

Smear fruit stem before or when flower

Improve fruit bearing

Cucumber

10-15

Seedling soaking 24h before transplant

Increase female flowers

Chinese cabbage, cabbage, cauliflower, sweet pepper etc

10-30

Foliage spray after picked

Improve fruit bearing

Lychee

100

Soaking 1-3min after picked

Prolong storage time

Wheat

20-30

Seed soaking 24h

Increase germination rate

Potato, gladiolus

10-20

Stem tuber soaking 6-12h

Seedling come out fast and growth better

Cotton

20

Seed soaking 24-48h

Seedling come out fast and growth better

Corn

10-20

Spray early female flowers

Increase setting rate

Grape, tomato

100

Spray or soak catkin when flowering

Increase fruit bearing

 




6-Benzylaminopurine Usage And Synthesis

Chemical Propertieswhite to light yellow crystal powder
Chemical PropertiesColorless to off-white or yellow powder. Corrosive.
Uses6-Benzylaminopurine can be used as inhibitor of respiratory kinase in plants.
uses6-Benzylaminopurine is a plant growth regulator that belongs to the class of first generation synthetic cytokinin used in agriculture.
6-Benzylaminopurine has been used:
to induce sprouting in plant materials.
in seed germination medium for culturing of seeds.
to modify Murashige and Skoog (MS) media for shoot initiation.
6-Benzylaminopurine, benzyl adenine (BAP) is a synthetic cytokinin which together with auxins elicits plant growth and development responses. BAP is a widely use cytokinin supplement to plant growth media such as Murashige and Skoog medium, Gamborg’s medium, and Chu’s N6 medium.
DefinitionChEBI: A member of the class of 6-aminopurines that is adenine in which one of the hydrogens of the amino group is replaced by a benzyl group.
Health HazardRecommended Personal Protective Equipment: Self-contained breathing apparatus, rubber gloves, acid goggles; Symptoms Following Exposure: Vapor is irritating when breathed at high concentrations. Contact with liquid causes irritation of skin and burning of eyes; General Treatment for Exposure: INHALATION: remove to fresh air; administer artificial respiration or oxygen if indicated; call a physician. SKIN AND EYES: wash with plenty of water; Toxicity by Inhalation (Threshold Limit Value): Data not available; Short-Term Exposure Limits: LD50 100 ppm, 4 hr; Toxicity by Ingestion: Grade 2; LD50 = 0.5 to 5 g/kg (rat); Late Toxicity: Data not available; Vapor (Gas) Irritant Characteristics: Vapors cause a slight smarting of the eyes or respiratory system if present in high concentrations. The effect is temporary; Liquid or Solid Irritant Characteristics: Minimum hazard. If spilled on clothing and allowed to remain, may cause smarting and reddening of the skin; Odor Threshold: Data not available.
Chemical ReactivityReactivity with Water No reaction; Reactivity with Common Materials: No reactions; Stability During Transport: Stable; Neutralizing Agents for Acids and Caustics: Not pertinent; Polymerization: Polymerizes upon exposure to heat; uncontrolled bulk polymerization can be explosive; Inhibitor of Polymerization: Methyl ether of hydroquinone: 15-100 ppm. Store in contact with air.
Agricultural UsesPlant growth regulator: A plant growth regulator used to lengthen and enhance the shape of apples and to increase the fruit set in pears. It increases the yield of pistachios and tomatoes. Not listed for use in EU countries. Registered for use in the U.S.
Trade nameABG® 3034; ACCEL®; AGTROL®; 6-BA®; BA® (growth stimulant); CHRYSAL BVB®; EXILIS®; PERLAN®; PROMALIN®; SD® 4901; SQ® 4609
Safety ProfileModerately toxic by ingestion andskin contact. Human mutation data reported. Whenheated to decomposition it emits toxic vapors of NOx.
Potential ExposureA polyamine plant growth regulator used to lengthen and enhance the shape of apples and to increase the fruit set in pears. It increases the yield of pistachios and tomatoes. Not listed for use in the EU countries.
ShippingUN3259 Amines, solid, corrosive, n.o.s, or Polyamines, solid, corrosive, n.o.s., Hazard class: 8; Labels: 8—Corrosive material, Technical Name Required.
Purification MethodsIt is purified by recrystallisation from aqueous EtOH. It has at 207 and 270nm (H2O), 268 nm max (pH 6), 274nm (0.1 N HCl) and 275nm (0.1 N NaOH). [Daly J Org Chem 21 1553 1956, Bullock et al. J Am Chem Soc 78 3693 1956, Beilstein 26 III/IV 3575.]
IncompatibilitiesMay react with strong oxidizers such as chlorates, peroxides, nitrates, etc. May release heat on contact with water. Solid and corrosive amines are chemical bases. Neutralize acids to form salts plus water in exothermic reactions. May be incompatible with isocyanates, halogenated organics, peroxides, phenols (acidic), epoxides, anhydrides, and acid halides. May generate flammable gaseous hydrogen in combination with strong reducing agents, such as hydrides.
Waste DisposalDissolve or mix the material with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber. All federal, state, and local environmental regulations must be observed.

6-Benzylaminopurine Preparation Products And Raw materials
Raw materialsMethanol-->Acrylic acid-->Poly(acrylic acid)
Preparation ProductsPoly(acrylic acid)-->Butyl acrylate-->Ethyl pyruvate-->Pyruvic acid-->PAINT-->acrylate ternary copolymer bound disulfide platinum complex catalyst-->Sodium polyacrylate-->Styrene-acrylic latex-->EAM resin adhesive modified with diisocyanate for orthodontias-->Lorcainide-->Atracurium besylate-->polyurethane photosensitive prepolymer-->sheeting sensitized glue-->acrylic resin coating finish-->Acrylic latex-->Adhesive for nonwoven fabric-->6-benzylaminopurine hydrochloride-->1-Isopropyl-4-piperidone-->N-(4-chlorophenyl)-1-isopropylpiperidin-4-amine-->coupling agent NBC-1-->Pressure sensitive adhesive-->THERMOPLASTIC ACRYLIC RESIN-->4-(4-(Chlorophenyl)imino)-1-isopropyl piperidine-->butadiene resin emulsion LHYJ-DS50-->Ethyl α-cyanoacrylate instantaneous adhesive-->2-Pentyl-3-methyl-2-cyclopenten-1-one-->methyl 2-(2′-hydroxy phenyl)-3-methoxy acrylate-->acrylic resin emulsion FX-1-->Silicone acrylic emulsion-->Water-soluble electrophoretic paint-->Construction emulsion BC-01-->modified acrylic resin emulsion SB-->sizing agent NBJ for jet loom-->flocculant TS-614-->nonformaldehyde resin finishing agent CN-NF^{3^}-->leather binder CAF-->WPT-S silicone modified water proof. fatliquoring and retanning agent-->HMP muti-functional retanning agent HMP


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